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Q.

Statement-1: Lithium's reaction with water is less vigorous than that of sodium. Statement-2: Lithium has small size and very high hydration energy.

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a

Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for Statement-1. 

b

Statement-1 is True, Statement-2 is True, Statement-2 is NOT a correct explanation for Statement-1

c

Statement-1 is True, Statement-2 is False. 

d

Statement-1 is False, Statement-2 is true.

answer is A.

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Detailed Solution

Because sodium is bigger than lithium and has a lower ionisation enthalpy, it reacts with water more forcefully than lithium. This is because sodium is a more electropositive metal. As we descend, the group's electropositive property grows as ionisation enthalpy decreases. Thus the option A is correct.

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Statement-1: Lithium's reaction with water is less vigorous than that of sodium. Statement-2: Lithium has small size and very high hydration energy.