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Q.

Statement-1 : NH4Cl and  NH4OH can be used to separate a mixture containing  Cr3+,Ni+2
Statement-2 : NH4Cl  increases (NH4+)  in NH4OH  thus increases ionic product of chromium (III)  hydroxide and it exceeds solubility product of Cr(OH)3 and Cr(OH)3 gets precipitated. 

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a

Statement-1 is False, Statement-2 is True.

b

Statement-1 is True, Statement-2 is False 

c

Statement -1 is True, Statement-2 is True; Statement-2 is a NOT correct explanation for Statement-1.

d

Statement -1 is True, Statement-2 is True; Statement-2 is a correct explanation for Statement-1.

answer is C.

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Detailed Solution

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(NH4Cl+NH4OH)  reagent precipitate the cation of  III  group only Al3+,Cr3+,Fe3+.
This is due to low dissociation of NH4OH  (common ion effect ).

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