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Q.

Statement 1: p-nitrophenol is a stronger acid than o-nitrophenol.

Statement 2: Intramolecular hydrogen bonding makes the o-isomer weaker than the p-isomer.

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a

Both Statements 1 and 2 are incorrect.

b

Statement 1 is incorrect and statement 2 is correct

c

 Statement 1 is correct and statement 2 is incorrect.

d

Both statements 1 and 2 are correct

answer is A.

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Detailed Solution

Due to intra molecular H-bonding between -OH group and -NO2 group, the proton in o-nitro phenol is less available for donation.

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