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Q.

Statement 1: Pb4+ compounds are stronger oxidising agent than Sn4+ compounds.

Statement 2: The higher oxidation states for the group 14 elements are more stable for the heavier members of the group due to 'inert-pair effect'.

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a

Both statements 1 and 2 are correct

b

Statement 1 is correct and statement 2 is incorrect

c

Statement 1 is incorrect and statement 2 is correct

d

Both statements 1 and 2 are incorrect

answer is B.

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Detailed Solution

Due to inert-pair effect, the higher oxidation states for the group 14 elements are less stable for the heavier members of the group and have a tendency to reduce to lesser oxidation state (i.e., These are stronger oxidation agent).

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Statement 1: Pb4+ compounds are stronger oxidising agent than Sn4+ compounds.Statement 2: The higher oxidation states for the group 14 elements are more stable for the heavier members of the group due to 'inert-pair effect'.