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Q.

Statement 1: Propene reacts with HBr in presence of benzoyl peroxide to yield 1-bromopropane.

Statement 2: In presence of peroxide, the addition of HBr to propane follows ionic mechanism.

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a

Statement 1 is correct and statement 2 is incorrect

b

Statement 1 is incorrect and statement 2 is correct

c

Both statements 1 and 2 are correct

d

Both statements 1 and 2 are incorrect

answer is B.

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Detailed Solution

Propene reacts with HBr in presence of benzoyl peroxide to give 1-bromopropane. In presence of peroxide, the addition of HBr to propene occurs by free radical mechanism.

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Statement 1: Propene reacts with HBr in presence of benzoyl peroxide to yield 1-bromopropane.Statement 2: In presence of peroxide, the addition of HBr to propane follows ionic mechanism.