Q.

Statement 1: Pyrrolidine (II) is more basic than pyrrole (I)

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Statement 2: Protonated pyrrole has delocalization of positive charge in aromatic ring.

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a

Both statements 1 and 2 are correct

b

Statement 1 is correct and statement 2 is incorrect

c

Statement 1 is incorrect and statement 2 is correct

d

Both statements 1 and 2 are incorrect

answer is B.

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Detailed Solution

In (I) lone pair of N is delocalized but not in (II). After protonation of (I) positive charge cannot participate in resonance (follow octet rule)

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Statement 1: Pyrrolidine (II) is more basic than pyrrole (I)Statement 2: Protonated pyrrole has delocalization of positive charge in aromatic ring.