Q.

Statement-1: Single NN bond is weaker than the single PP bond.

Statement-2: In NN bond there is high interelectronic repulsion of the non-bonding electrons, resulting in weaker bond.

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a

Statement-1 is False, Statement-2 is True.

b

Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for Statement-1.

c

Statement- 1 is True, Statement- 2 is True, Statement-2 is NOT a correct explanation for Statement-1.

d

Statement-1 is True, Statement- 2 is False.

answer is A.

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Detailed Solution

Because N is smaller than P, a single N-N bond is weaker than a P-P bond. N bond length decreases as N size decreases. As a result, the lone pair of electrons on both N atoms repel each other, causing the N-N bond to become unstable or weak. Because of the larger size of the P atom, the P-P bond length is longer and the lone pair-lone pair repulsion between P -atoms is lower, making the PP bond stronger than the N-N bond.

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