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Q.

Statement-1: Sodium hydride can be used as an oxidizing agent.

Statement-2: The lone pair of electrons on nitrogen pyridine makes it basic.

Chose the correct answer from the options given below  

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a

Both Statement-1 and Statement-2 are correct

b

Statement-1 is false and Statement-2 is true.

c

Both Statement-1 and Statement-2 are false

d

Statement-1 is false and Statement-2 is correct

answer is D.

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Detailed Solution

Sodium hydride releases hydride ion along with sodium ion.

NaHNa++H

Therefore, acts as a reducing agent.

Lone pairs of N present in sp2 hybridized orbital which is perpendicular to pi-system of ring. Therefore, lone pairs of N is not involved in resonance. Due to the availability of lone pair on N in pyridine, it acts as a base.


Therefore, c is the correct option.

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