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Q.

Statement 1: Solubility of haloalkane in water is low.

Statement 2: Energy required to overcome attractions between haloalkane molecules & the energy raquired to break H-bonds in water are much higher than the new attractions developed between haloalkane and water

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a

Statement 1 is incorrect statement 2 is correct

b

Statement 1 is correct statement 2 is incorrect

c

Both statements 1 and 2 are correct

d

Both statements 1 and 2 are incorrect

answer is A.

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Detailed Solution

I) Intermolecular Attractions between haloalkanes - dipole-dipole 

Intermolecular Attractions between water molecules - H-bonding

II) Attractions developed between R-X molecules and water are weak 

Energy required to break the attractions in I case dominate II 

 alkyl halides are insoluble in water

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