Q.

Statement 1: The free gaseous chromium atom has six unpaired electrons.

Statement 2: Half-filled orbital has greater stability than fully filled.

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a

Statement 1 is incorrect statement 2 is correct

b

Statement 1 is correct statement 2 is incorrect

c

Both statements 1 and 2 are correct

d

Both statements 1 and 2 are incorrect

answer is B.

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Detailed Solution

Statement 1: True, Electron configuration of Cr(g) is Ar183d54s1 and, therefore, it has six unpaired electrons.

Statement 2: False, Fully filled orbital is more stable than half filled orbital on account of more number of exchange of electrons resulting into the greater release of exchange energy.

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Statement 1: The free gaseous chromium atom has six unpaired electrons.Statement 2: Half-filled orbital has greater stability than fully filled.