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Q.

Statement 1: The lowest oxide of a transition metal (say, chromium, atomic number 24) is basic whereas the highest oxide is usually acidic.

Statement 2: Cr2O3 is amphoteric in nature.

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a

Statement 1 is incorrect statement 2 is correct

b

Statement 1 is correct statement 2 is incorrect

c

Both statements 1 and 2 are correct

d

Both statements 1 and 2 are incorrect

answer is A.

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Detailed Solution

Both are correct statements but statement 2 is not correct explanation of statement 1. As the oxidation states of metals increase, the electronegativity values also increase. As a result the difference of electronegativities between metal and oxygen decreases and, therefore, acidic character of oxides increase.

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