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Q.

Statement 1: The solubility of salts of weak acid and strong base increases with increase in pH.

Statement 2: At lower pH, equilibrium shifts in forward direction in the ionization of salt of weak acid and strong base

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a

Statement 1 is incorrect statement 2 is correct

b

Statement 1 is correct statement 2 is incorrect

c

Both statements 1 and 2 are correct

d

Both statements 1 and 2 are incorrect

answer is C.

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Detailed Solution

S=KSPH++KaKa12

Thus solubility ‘S’ increase with increase in H+or in pH;

Alternate method;

Na3PO43Na++PO4-3; At lower pH, the H+ added removes phosphate ion to form a weak acid; Equilibrium shifts in forward direction

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