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Q.

Statement 1: The total energy of two molecular orbitals, however, remains the same as that of two original atomic orbitals.
Statement 2: The energy of the antibonding orbital is raised above the energy of the parent atomic orbitals that have combined and the energy of the bonding orbital has been lowered than the parent orbitals.

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a

Statement 1 is correct and statement 2 is incorrect.

b

Statement 1 is incorrect and statement 2 is correct.

c

Both statements 1 and 2 are incorrect.

d

Both statements 1 and 2 are correct.

answer is A.

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Detailed Solution

According to assumptions of MOT, the atomic orbitals which undergo LCAO must have the comparable energy because each specific orbital have its own specific energy depending upon various quantum number and their sum.

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