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Q.

Statement-1 : [V(CO)6] can not act as oxidising agent.
Statement-2 : It can not be reduced by reducing agent.

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a

Statement-1 is false, statement-2 is false.

b

Statement-1 is true, statement-2 is false.

c

Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for statement-1.

d

Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1.

answer is D.

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Detailed Solution

The EAN value of [V(CO)6] is 35, so it has tendency to gain 1 more electron to achive the EAN value equal to nearest noble gas Kr (36), so it acts as oxidising agent.

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Statement-1 : [V(CO)6] can not act as oxidising agent.Statement-2 : It can not be reduced by reducing agent.