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Q.

Statement 1: Withdrawing group present only at ortho & para position shows effect but not at meta position on nucleophilic substitution of chloro benzene

Statement 2: Carbanion formed is stabilizes through resonance by the presence of -NO2 gp ortho & para but not when present at meta position 

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a

Both statements 1 and 2 are correct

b

Statement 1 is correct statement 2 is incorrect

c

Statement 1 is incorrect statement 2 is correct

d

Both statements 1 and 2 are incorrect

answer is A.

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Detailed Solution

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Intermediate is carbanion, negative charge delocalized at ortho & para position. 

 carbanion is stabilized by EWG NO2,CHO....etc

Carbanion is destabilized by EDG OCH3,CH3

Greater the number of  -NO2 groups at ortho & para position more will be the rate of reactivity towards nucleophilic substitution

-NO2 gp at meta position has negligible effect. In fact, reactivity of nucleophilic substitution

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