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Q.

Statement-1: Cr2+ is a stronger reducing agent than Fe2+.

Statement-2: In aqueous medium, d3 is more stable than d5 configuration.

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a

Statement-1 is False, Statement-2 is True.

b

Statement--1 is True, Statement-2 is False. 

c

Stat.ement-1 is True, Statement-2 is True; Statemen-2 is a correct explanation for Statement-1. 

d

Statement-1 is True, Stat.ement-2 is True, Statement-2 is NOT a correct explanation for Statement-1.

answer is A.

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Detailed Solution

The d3 configuration of the Cr3+ ion t2g3eg0 makes Cr3+ stable by supplying crystal field stabilisation energy. As a result, Cr2+ ion can readily oxidised into Cr3+ and function as a powerful reducing agent.

Cr2+Cr3++e
Compared to the outer orbital (high spin) complex, the inner orbital (low spin) complex is more stable. Therefore, in an aqueous medium, the d3 form is more stable than the d5 configuration.

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