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Q.

Statement 1: CsCl has body-centred cubic arrangement.

Statement 2: CsCl has one Cs+ ion and 8 Cl- ions in its unit cell.

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a

Both Statement 1 and Statement 2 are true.

b

Both Statement 1 and Statement 2 are false

c

Statement 1 is true but Statement 2 is false.

d

 Statement 1 is false but Statement 2 is true.

answer is C.

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Detailed Solution

CsCl follows 8 : 8 type of arrangement.

That means, Co.No. of Cs+ ion = 8; and Cs+ion present in cubic voids or body centre Co.No. of Cl-ion = 8; and ions follows simple cubic arrangement. They  occupy corners of the cube.

Number of Cs+ions per unit cell = 1×1 =1 Number of Cl- ions per unit cell =8×18=1

Therefore, CsCl has one Cs+ ion and one Cl- ion in its unit cell. 

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