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Q.

Statement 1: Ecell° should have a positive value for galvanic cell to function.
Statement 2:  Ecathode <Eanode for a feasible reaction, with reference to SRP
 

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a

Both statements 1 and 2 are correct

b

Both statements 1 and 2 are incorrect

c

Statement 1 is correct statement 2 is incorrect

d

Statement 1 is incorrect statement 2 is correct

answer is C.

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Detailed Solution

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Statement 1 is true but statement 2 is false. 

Feasibility of chemical reaction depends on Gibb's free energy which is related to Ecell  as, ΔG=nFEcell 
When value of Ecello is positive then Go becomes negative. Hence, reaction becomes feasible.
Correct reason is  Ecathode >Eanode .

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