Q.

Statement 1: N3- is a weaker base than NH2-

Statement 2: The lone pair of electrons on N atom in N3- is in a sp2-orbital while in NH2- it is in an sp3-orbital.

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a

Both statements 1 and 2 are correct

b

Statement 1 is incorrect and statement 2 is correct

c

Both statements 1 and 2 are incorrect

d

Statement 1 is correct and statement 2 is incorrect

answer is A.

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Detailed Solution

Basicity depends upon availability of lone pair of electrons. Since N3 is in SP2 - orbital, its lone pair is less available as compared to NH2 . Thus, N3- is a weaker base than NH2 .

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