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Q.

Statement-1: Na+and Al3+are isoelectronic but the magnitude of ionic radius or Al3+is less than that of Na+.

Statement-2: The magnitude of effective nuclear charge of the outer most shell electrons in Al3+is greater than that in Na+,

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a

Statement-1 is True, Statement-2 is False.

b

Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for Statement-1.

c

Statement-1 is True, Statement-2 is True, Statement-2 is NOT a correct explanation for Statement-1.

 

d

Statement-1 is False, Statement-2 is True.

answer is A.

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Detailed Solution

Effective nuclear charge rises with increasing atomic number Z for isoelectronic species (with increase in protons). Al3+<Na+'s ionic radius decreases as a result, resulting in size reduction.

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