Q.

Statement-1: NF3 has little tendency to act as a donor molecule. 

Statement-2: The highly electronegative F atoms attract electrons and these moments partly cancel the moment from the lone pair.

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a

Statement-1 is False, Statement-2 is True.

b

Statement-1 is True, Statement-2 is False

c

Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for Statement-1

d

Statement-1 is True, Statement-2 is True, Statement-2 Is NOT a correct explanation for Statement-1

answer is A.

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Detailed Solution

NF3 has little tendency to act as a donor molecule" is correct

Because the bond angles in NH3 and NH3 are 103.3° and 103.2°, respectively, indicating that the polarity difference is attributable to differences in bond polarities rather than molecular geometry. Because of these disparities in the availability of unshared electron pairs, NH3 does not operate as an electron pair donor.

"The highly electronegative F atoms attract electrons and these moments partly cancel the moment from the lone pair" is correct because higher nuclear charge value will result in a higher electronegativity value. This occurs because an increase in nuclear charge creates stronger electron attraction.

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Statement-1: NF3 has little tendency to act as a donor molecule. Statement-2: The highly electronegative F atoms attract electrons and these moments partly cancel the moment from the lone pair.