Q.

Statement 1: RClorRBrNaIRIFinkelstein reaction  acetone is the solvent used

Statement 2: NaCl (or) NaBr the byproducts are insoluble in dry acetone which facilitates the forward reaction

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a

Statement 1 is incorrect statement 2 is correct

b

Statement 1 is correct statement 2 is incorrect

c

Both statements 1 and 2 are correct

d

Both statements 1 and 2 are incorrect

answer is A.

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Detailed Solution

RX+NaIDry acetoneRI+NaXX=Cl,Br

Ionic nature of NaCl > NaBr > NaI

NaCl and NaBr are insoluble in acetone. They can be removed easily

According to Lechatlier's principle removal of products favours forward reaction. 

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