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Q.

 Statement (A) : σ  bond has independent existence.

Statement (B) : Free rotation of atoms is not possible around  π - bond

 Statement (C) : π  - bond is more reactive than σ   bond.

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a

A and B are correct but c is incorrect.

b

A,B are incorrect and C is correct 

c

All the above statements are incorrect

d

All the above statements are correct

answer is A.

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Detailed Solution

The σ bond may exist either alone or along with π bonds.

 Free rotation is not possible around the π bond.

π bonds are more reactive because electron cloud is more exposed to attacking species.

All the three statements are correct.  Hence option A is correct answer.

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