Statement A: Azeotropic mixtures are formed only by non-ideal solutions and they may have boiling points either greater than both the components or less than both the components.
Statement B: The composition of the vapour phase is same as that of the liquid phase of an azeotropic mixture.

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Statement A is true but Statement B is false.

Both Statement A and Statement B are false

Statement A is false but Statement B is true.

Both Statement A and Statement B are true

answer is A.

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Detailed Solution

Non-ideal solutions with positive deviation i.e., having more vapour pressure tan expected, boil at lower temperature while those with negative deviation boil at higher temperature than those of the components.

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