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Q.

Statement (a) : CO2 has no dipole moment, whereas SO2 and H2O have dipole moment 

Statement (b) : SnCl2is ionic, whereas SnCl4 is covalent.
Which of the following is correct?

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a

(a) is correct but (b) is not correct 

 

b

Both (a) and (b) are correct 

 

c

Both (a) and (b) are not correct 

 

d

(a) is not correct but (b) is correct

answer is C.

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Detailed Solution

(a) CO2 has linear structure while SO2and H2O have V-shaped structures. Hence, dipole moment in CO2 is cancelled out but SO2 and H2O posses a dipole moment.

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(b) Low charge on the cation favors the formation of Ionic bond. Hence SnCl2(Sn+2) is Ionic and SnCl4(Sn+4) is covalent.

 Tin (II) chloride ionic or covalent? In SnCl2, Sn has +2 oxidation state. In accordance to Fajan's rule, the central metal with more oxidation number will be to be more covalent. Therefore, SnCl4 is more covalent than SnCl2.

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