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Q.

Statement (A): Each sp hybrid orbital has 50% s character

Statement (B): Each sp hybrid orbital has 50% p character

Statement (C): πbond is less reactive than σ bond

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a

A, B are correct and C is incorrect

b

All the above statements A, B and C are incorrect

c

A, B are incorrect and C is correct

d

All the statements A, B and C are correct

answer is C.

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Detailed Solution

The sp hybrid orbital is formed by the inter mixing of  one pure s-orbital and 1 pure p-orbital.  So, the resultant sp orbital should have 50% s character and 50% p character.  Therefore, statement-I and II are correct.  As we know that the sigma bond was formed by the end on end inter nuclear axis of both the atomic orbitals.  Hence it is a strong bond.  Coming to pie bond it is formed by the lateral overlapping or sidewise overlapping of two pure p-orbitals or one p-orbital and one d-orbital or two pure d-orbitals.  So the pie bond the pie bond is a weak in strength than sigma bond.  Hence it is more reactive than sigma bond. Therefore statement-III is incorrect.
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