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Q.

Statement A: On dilution, the equivalent as well molar conductivity of the solution increases.

Statement B: with dilution, the number of current carry­ing particles per cm3 increases.

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a

Both Statement A and Statement B are true 

b

Both Statement A and Statement B are false

c

Statement A is true but Statement B is false. 

d

Statement A is false but Statement B is true. 

answer is C.

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Detailed Solution

On dilution, the number of current carrying particles per cm3 decreases and hence specific conductivity decreases. Λeq and Λm increase with dilution because Λeq=Specific conductivity x volume of solution containing 1 g eq. of the electrolyte 

and Λm=Specific conductivity x volume of solution containing 1 mole of the electrolyte and volume increases much more and hence decrease in specific conductivity. 

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