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Q.

Statement A: The photochemical reactions H2+Cl22HCl and H2+Br22HBr have equal quantum efficiencies.

Statement B: Both the reactions proceed by different mechanism.

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a

Both Statement A and Statement B are true 

b

Both Statement A and Statement B are false

c

 Statement A is true but Statement B is false. 

d

Statement A is false but Statement B is true. 

answer is D.

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Detailed Solution

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H2+Cl22HCl has much higher quantum efficiency than  H2+Br22HBr

The first step of secondary process of H2+Cl22HCl is exothermic while the same for H2+Br22HBr is endothermic. 

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