Q.

Statement (I) : Acidic strength of H2S > H2O

Statement (II) : S-H bondenergy < O-H bond energy

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a

Both (I) & (II) are true

b

Both (I) & (II) are false

c

(I) is false & (II) is true

d

(I) is true & (II) is false

answer is A.

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Detailed Solution

In the hydrides of 14th , 15th , 16th & 17th group ,

Acidic strength is decided by X-H bond enthalpy but not by X-H bond polarity

Down the group as the size of atom increases , affinity with H-atom decreases,

X-H bond enthalpy decreases and thus acidic strength and reducing power increases

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