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Q.

Statement I : All oxo acids of phosphorous have P-OH bond

Statement II : All oxo acids of phosphorous have P=O bond

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a

Both (I) & (II) are True

b

Both (I) & (II) are false

c

(I) is true & (II) is false

d

(I) is false & (II) is True

answer is A.

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Detailed Solution

-O-H bond is responsible for basicity

No. of -OH bonds = Basicity

All Oxo acids must contain -OH bond

In all Oxo acids of 'P' , Phosphorous atom is surrounded by three σ (sigma) bonds

( P-H (or) P-OH (or) P-O-P (or) P-P) and one P=O

Thus each 'P' atom is surrounded by three single and one double bond

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