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Q.

Statement-I : Ammonolysis of excess alkylhalide  in a sealed tube at 373 K is the best method to prepare 1° amines.

Statement-II : Excess ammonia with alkyl halide at 373 K gives 1° amine as major product 

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a

Both statements I and II are correct

b

Statement-I is correct and statement-II is incorrect

c

Statement-I is incorrect and statement-II is correct

d

Both statements I and II are incorrect

answer is C.

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Detailed Solution

I) Ammonolysis of alkyl halide gives a mixture of 1° amine, 2° amine, 3° amine and a 4° salt. This mixture is difficult to separate. This is not a suitable method to prepare 1° amine.

R-X(Excess)-HXNH3R-NH2-HXR-XR2NH-HXR-XR3N RXR4N+X-;

II) R-X+NH3excessR-NH2major+HX

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Statement-I : Ammonolysis of excess alkylhalide  in a sealed tube at 373 K is the best method to prepare 1° amines.Statement-II : Excess ammonia with alkyl halide at 373 K gives 1° amine as major product