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Q.

Statement I : Aq. Na2CO3 solution is more basic than that of aq. NaHCO3
Statement II : The extent of hydrolysis of Na2CO3 is less than that of NaHCO3

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a


Statement I and II are correct and statement II is the correct explanation of I

b

Statement I and II are correct but statement II is not the correct explanation of I

c

Statement - I is correct and Statement- II is incorrect

d

Both statement - I  and statement - II are incorrect

answer is C.

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Detailed Solution

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aq.Na2CO3 is more basic than that of NaHCO3

\large CO_3^{ - 2}\; + \;2{H_2}O\; \to \;{H_2}O\; + \;C{O_2}\; + \;2O\mathop H\limits^ -
\large HCO_3^ \ominus \; + \;{H_2}O\; \to \;{H_2}O\; + \;C{O_2}\; + \;O\mathop H\limits^ \ominus


Both undergoes anionic hydrolysis, but the number of  OH-ion produced by bicarbonate ion
aq solution of Na2CO3 is more basic than that of aq.solution of NaHCO3
→ And the extent of hydrolysis of Na2CO3 is more than that of NaHCO3
Statement - I is correct & state - II is incorrect.

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