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Q.

Statement I : Be forms [BeF4]2- but Al forms [AlF6]3-

Statement II : Be does not have d-orbitals in the valence shell but Al has

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a

Statement I and II are correct 

b

Statement I is incorrect and II  correct 

c

Statement - I is correct and statement - II is incorrect

d

Both statement I and statement II are false

answer is A.

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Detailed Solution

"Be" Maximum covalency is 4. Since in its valency shell [n=2] it has  3-orbitals only, those are one 2s & three 2p orbitals
 

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Where as in case of "Al" due the presence of empty 3d-orbitals in its valency shell, it can extends its valency upto "6"
Ex :- "Al" forms [AlF6]-3

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 Statement - I and Statement - II are correct

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