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Q.

Statement I : CeO2 can be used for oxidation of aldehydes and ketones
Statement II : Aqueous solution of EuSO4 is a strong reducing agent.

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a

Statement I is true but statement II is false

b

Both statement I and statement II are false

c

Both statement I and statement II are true

d

Statement I is false but statement II is true

answer is A.

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Detailed Solution

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Cerium is the second element in its series, and it shows the +3 oxidation state characteristic of the series, it also has a unstable +4 state. In the oxide CeO2 it has +4 state and it can reduce itself and oxidise the substrate.

Eu2+ is a strong reducing agent because Eu3+ is more stable than Eu2+. Yb in +2 oxidation states acquires half filled-4f7 and fully filled-4f14 configuration. Tb in +4 state has 4f7 half-filled stable configuration but it readily gets reduced to common oxidation +3 state.

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