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Q.

Statement I : Fluorination of Ethane is explosive.

Statement II : Iodination of Ethane is reversible. 

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a

Both Statements I and II are correct

b

Statement I is correct and Statement II is incorrect

c

Statement I is incorrect and Statement II is correct

d

Both Statements I and II are incorrect

answer is A.

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Detailed Solution

Statement I : F2 is highly reactive towards free radical reactions.

                       Propagation steps are highly exothermic and explosive.

Statement II : C2H5H+I2 C2H5I+HI 

HI is a good reducing agent. 

It reduces C2H5I to C2H6.

Backward reaction occurs.

To prevent backward reaction, the reaction is carried out in presence of oxidizing agents.

Ex : HIO3,HIO4,HNO3 etc.

These oxidizing agents oxidize HI to I2 and prevent backward reaction.

5HI+HIO3 3I2+3H2O

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