Q.

Statement I ; High value of equilibrium constant always indicates that rate of forward reaction is greater than rate of backward reaction.

Statement II ; Magnitude of equilibrium constant always increases with increase in temperature.

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a

Statements I and II are incorrect

b

Statements I and II are correct

c

Statement I  is incorrect and statement II is correct

d

Statement I  is correct and statement II is incorrect 

answer is D.

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Detailed Solution

Statement I ; High value of equilibrium constant always indicates that forward reaction is favoured.

                       Keq (thermodynamic property) has no relation with rate of reaction (kinetic property).

Statement II ; Magnitude of equilibrium constant increases with increase in temperature for endothermic reactions.

                       Magnitude of equilibrium constant decreases with increase in temperature for exothermic reactions.

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