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Q.

Statement I : Potassium permanganate on heating at 573 K forms potassium manganate.
Statement II : Both potassium permanganate and potassium manganate are tetrahedral and paramagnetic in nature.

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a

Statement I is true but statement II is false

b

Both statement I and statement II are false

c

Both statement I and statement II are true

d

Statement I is false but statement II is true

answer is D.

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Detailed Solution

KMn+7O4Diamagnetic573K K2Mn+6O4one unpaired e-(paramagnetic)+MnO2+O2

Both KMnO4 and K2MnO4 are tetrahedral.

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