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Q.

Statement I : Since HClO4 is a stronger acid than H2SO4, HCl and HNO3,and therefore it has a greater tendency to donate proton in comparison to others.

Statement II : Perchloric acid is stronger acid than H2SO4 in acetic acid.

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a

Statement I and II are correct

b

Statement I  is correct and Statement II is incorrect

c

Statement - I is incorrect and Statement II is correct

d

Both statement - I  and statement - II are False

answer is A.

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Detailed Solution

Perchloric acid will have a more stable conjugate base in acetic acid due to greater extent resonance in the conjugate base. Question is based on the levelling effect of water. Only H+ can exist as a strong acid in water.

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Statement I : Since HClO4 is a stronger acid than H2SO4, HCl and HNO3,and therefore it has a greater tendency to donate proton in comparison to others.Statement II : Perchloric acid is stronger acid than H2SO4 in acetic acid.