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Q.

Statement I : Temperature has very little effect on solubility of sodium chloride
Statement II : Pure sodium chloride is deliquescent

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a

Statement I is incorrect and statement II is correct 

b

Statement - I is correct and Statement- II is incorrect

c

Statement I and II are correct

d

Both statement - I  and statement - II are incorrect

answer is C.

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Detailed Solution

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Statement - I is true & Statement - II is false
The solubility of NaCl does not change appreciably with increase in temperature
→ Hydration enthalpy of NaCl is -784.0KJ/mole,
Where as lattice enthalpy of NaCl is + 788.0KJ/mole
Since ΔHsolution of NaCl is +4.0Kj/mole,i.e., ΔHsolution value is negligibly small and hence no effect of temperature on its solubility.
→ Common salt [NaCl] generally associated with impurities like MgCl2 & CaCl2 .Due to the presence of CaCl2 & MgCl2 it behaves as deliquescent.
But the pure form of NaCl [Without MgCl2 , CaCl2] Can't shows deliquescent nature as its hydration energy is low due to its large size

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