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Q.

Statement-I : The blue precipitate formed by the action of K4FeCN6  on  Fe3+ and by that of K3FeCN6  on  Fe2+  have the same composition.
Statement-IIFeCN63 oxidises  Fe2+  to  Fe3+ and itself gets reduced to FeCN64  Correct relation is

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a

Statement –I is correct but statement –II is false

b

Statement –I is incorrect but statement – II is correct

c

Both are correct statements and statement –II  is correct explanation for statement-I

d

Both are correct statements and statement –II  is  not correct explanation for statement-I

answer is A.

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Detailed Solution

 In both case complex formed is Fe4Fe(CN)63

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