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Q.

Statement-I : The product obtained by the reaction of primary amine with benzene sulphonyl chloride is soluble in alkali.

Statement-II : N-alkyl benzene sulphonamide contains a strongly acidic hydrogen atom.

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a

Both statements I and II are correct

b

Statement-I is incorrect and statement-II is correct

c

Both statements I and II are incorrect

d

Statement-I is correct and statement-II is incorrect

answer is A.

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Detailed Solution

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The product contains a hydrogen atom attached to nitrogen atom. This hydrogen atom is strongly acidic because -NH- group is attached to strong electron withdrawing -SO2C6H5 group.

Thus N-alkyl benzene sulphonamide is soluble is alkali.

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