Q.

Statement  I : 1 mol of iron (Fe) reacts completely with 0.65 mol O2 to give a mixture of only FeO and Fe2O3.
Statement  II : Mole ratio of FeO & Fe2O3 in the product  mixture is 4 : 3.
In the light of the above statements, choose the most appropriate answer from the options given below: 

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a

Both statement  I and statement  II  are incorrect.

b

Both statement  I and Statement  II are correct.

c

Statement  I is correct, Statement  II is incorrect.  

d

Statement  I is incorrect, statement  II is correct.

answer is A.

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Detailed Solution

 Fe+1/2O2 FeaO
2Fe+3/2O2 Feb2O3
Let a moles of  FeO and b moles of  Fe2O3  is formed.
 moles of Fe used = a+2b=1
 moles of  O2=a+3b2=0.65
 b = 0.3 and a = 0.4 

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