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Q.

Statement I:  σ1s* has higher energy than σ2s orbital.
Statement II :  Any antibonding orbital has higher energy than any bonding orbital.

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a

Statement I and Statement II are true.

b

Statement I is true and  statement II is false.

c

Statement I is false and Statement II is true.

d

Statement I and Statement II are false.

answer is D.

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Detailed Solution

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In (ABMO) a nodal plane is present between the nuclei of  bonded  atoms leading to repulsions
No nodal plane between the nuclei of two bonded atoms in BMO
Energy of ABMO > Energy of BMO (involving same orbital)
Energy of:  σ1s< σ1s*<  σ2s< σ2s*

I and II are false

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