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Q.

Statement I: A covalent bond may be cleaved either by heterolytic cleavage or by homolytic cleavage.
Statement II: Heterolytic cleavage of CH3Br will give CH3 and Br free radicals.

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a

Both Statement I and Statement II are correct and Statement II is the correct explanation of Statement I.

b

Both Statement I and Statement II are correct but Statement II is not the correct explanation of Statement I.

c

Statement I is correct but Statement II is incorrect

d

Both Statement I and Statement II are incorrect.

answer is C.

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Detailed Solution

A covalent bond may be cleaved either by (i) heterolytic cleavage, or by (ii) homolytic cleavage.
In heterolytic cleavage, the bond breaks in such a fashion that the shared pair of electrons remains with one of the fragments.

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In homolytic cleavage, one of the electrons of the shared pair in a covalent bond goes with each of the bonded atoms.

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Statement I: A covalent bond may be cleaved either by heterolytic cleavage or by homolytic cleavage.Statement II: Heterolytic cleavage of CH3Br will give CH3 and Br free radicals.