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Q.

Statement I : A solution of FeSO4 can be stored in a copper vessel.

Statement II : E0 of Cu2+/Cu < E0 of Fe2+/Fe

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a

Statement I and II are correct

b

Statement I is correct and II is incorrect

c

Statement I is incorrect and statement II is correct

d

Statement I & II are  incorrect

answer is B.

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Detailed Solution

begin{gathered} E_{F{e^{ + 2}}/Fe}^0; = ; - 0.44V \ E_{C{u^{ + 2}}/Cu}^0; = ; + 0.34 \ end{gathered}


Cu+2 →Cu and Fe →Fe+2 is spontaneous because 

large E_{C{u^{ + 2}}/Cu}^0; = ; + 0.34; > ;E_{F{e^{ + 2}}/Fe}^0; = ; - 0.44V


Fe + CuSO4 → FeSO4 + Cu is a spontaneous reaction
Thus FeSO4 cannot be reduced by Cu
FeSO4 Can be stored in 'Cu' vessel
Statement I is correct but statement II is false

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