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Q.

Statement-I: All F-S-F angles in SF4 are greater than 90° but less than 180° 

Statement-2: The bond pair-bond pair repulsion is weaker than lone pair-bond pair repulsion

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a

Statement-I is True, Statement-2 is True; Statement-2 is a correct explanation for Statement-I.

b

Statement-1 is False, Statement-2 is True.

c

Statement-1 is True, Statement-2 is False

d

Statement-I is True, Statement-2 is True, Statement-2 Is NOT a correct explanation for Statement-I.

answer is D.

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Detailed Solution

"The bond pair-bond pair repulsion is weaker than lone pair-bond pair repulsion" is correct 

The repulsion is stronger because the electrons in a lone pair are not involved in bonding and are thus free. The repulsion between a lone pair and a bond pair is somewhat greater than that between a bond pair and a bond pair due to one free electron.

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