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Q.

Statement-I: Aniline cannot be prepared by Gabriel phthalimide synthesis

Statement-II: Aniline is a primary aryl amine.

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a

Both statements I and II are correct

b

Statement-I is incorrect and statement-II is correct

c

Both statements I and II are incorrect

d

Statement-I is correct and statement-II is incorrect

answer is A.

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Detailed Solution

The main step in Gabriel phthalimide synthesis is 

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‘X’ on alkaline hydrolysis gives R-NH2

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In step I instead of R - X if we take C6H5-X  we  get  C6H5NH2. But this is not possible;

C6H5-X cannot be attacked by the nucleophile because C6H5-X stabilizes through resonance, C-X acquires double bond character;

It is non reactive towards nucleophilic substitution;

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