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Q.

Statement-I: Aniline is more stable than anilinium ion.

Statement-II: The proton acceptability nature of aniline is less than that of ammonia.

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a

Statement I is false and  Statement II is true

b

Statement I is true and  Statement II is false

c

Both Statement I and  Statement II are false

d

Both Statement I and  Statement II are true

answer is A.

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Detailed Solution

In basic media, it means there will be an attack by a proton and the aniline is protonated to an anilinium ion.

C6H5NH2aniline+protonationC6H5NH3+anilinium ion

Anilinium ion, due to the positive charge on it, shows an -I effect, so it will not remain like O and P-directed towards strong acid. It will behave as meta-directing as the -I effect is more on ortho(O) and para (P) positions and less on meta positions, so when an electrophile attacks, it attacks faster on meta - position.

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