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Q.

Statement I : BeO and Al2O3 are amphoteric
Statement II : Be and Al are made passive by HNO3

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a

Statement I and II are correct 

b

Statement I is incorrect and statement II is correct

c

Statement - I is correct and Statement - II is incorrect

d

Both statement - I and statement - II are incorrect

answer is A.

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Detailed Solution

BeO and Al2O3 are amphoteric in nature.

  1. The oxides of both Be [BeO] and Al[Al2O3] are amphoteric and hence they dissolve in NaOH solution as well as in HCl
    BeO + 2HCl → BeCl2 + H2O
     
large BeO; + ;2NaOH; to ;mathop {N{a_2}Be{O_2}}limits_{Sod.Berrylate} ; + ;{H_2}O


Al2O3 + 6HCl → 2AlCl3 + 3H2O
 

Al2O3+2NaOH2NaAlO2+H2O

Be and Al become passive (resistant) on reaction with concentrated nitric acid due to formation of protective oxide layer on the surface of the Be and Al metals.

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