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Q.

Statement-I: Bromobenzene upon reaction with Br2/Fe gives 1,4− dibromobenzene as the major product.

Statement-2: In bromobenzene, the inductive effect of the bromo group is more dominant than the mesomeric effect hence incoming electrophile is directed to meta position.

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a

Statement-1 is true, Statement -2 is false.

b

Statement-1 is true, Statement-2 is true; 
Statement-2 is a correct explanation for Statement-1.

c

Statement-1 is false, Statement -2 is true.

answer is C.

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Detailed Solution

The mesomeric action of bromine controls its orientation. Its +M action stabilises the arenium ion.

In bromobenzene, the bromo group's inductive impact predominates over the mesomeric effect, which makes the ring activity less activating than in benzene.

Statement 1 is true, but statement 2 is false.

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Statement-I: Bromobenzene upon reaction with Br2​/Fe gives 1,4− dibromobenzene as the major product.Statement-2: In bromobenzene, the inductive effect of the bromo group is more dominant than the mesomeric effect hence incoming electrophile is directed to meta position.